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根据本文系列I提出的电极/溶液界面溶剂化层偶极取向分布模型,拟合计算Ag(111)、Ag(100)及Ag(110)/水溶液界面的内层微分电容(C_1)～表面电荷密度(σ)变化关系。表明在银电极上,吸附水分子似分别稳定在金属原子点阵的顶位(111)或穴位(100)及(110)。讨论了溶剂化层的结构与性质对C_1～σ曲线可能产生的影响。
According to the dipole orientation distribution model of the solvation layer of the electrode / solution interface presented in the series I of this article, the inner differential capacitance (C 1) ~ surface charge of the Ag (111), Ag (100) and Ag Density (σ) changes in the relationship. It is indicated that on the silver electrode, the adsorbed water molecules are respectively stable at the top position (111) or the acupoints (100) and (110) of the metal atom lattice. The possible influence of the structure and properties of solvates on the C_1 ~ σ curves is discussed.