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本文在海水中无机离子交换的平衡理论研究方面,取得了如下三个方面的成果:(1)提出海水中无机离子交换的分级平衡理论,这理论也适用于一般水溶液体系,并引入平均离子交换数,它可由实验测得,利用的基本方程式(11),提出了三种计算离子交换产物的生成常数的一般数学处理,(2)定量地讨论和推导了离子交换分级平衡理论与吸附理论的关系,并用铀-水合氧化钛体系等的实验数据作了验证,结果良好,(3)将无机离子交换的分级平衡理论用来解释无机离子交换中的最重要的实验事实——离子交换率与pH的关系,并提出了两种计算K的方法,运用了若干个体系的实验数据作了具体计算,理论和实验结果一致。
In this paper, the balance of inorganic ion exchange in seawater theory, made the following three aspects of the results: (1) proposed seawater inorganic ion exchange grading theory, this theory also applies to the general aqueous system, and the introduction of average ion exchange Which can be determined experimentally using the general equation (11), using three general mathematical calculations to calculate the generation constants of the ion exchange products. (2) Quantitatively discuss and derive the ion exchange equilibrium theory and the adsorption theory (3) The theory of fractional equilibrium of inorganic ion exchange is used to explain the most important experimental fact in inorganic ion exchange - ion exchange rate and pH, and put forward two methods to calculate K, using a number of experimental data system made a specific calculation, the theoretical and experimental results.