Synthesis and optical activity of isosorbide chiral derivative containing fluorocarbon group as chir

• 出 处: Chinese Chemical Letters
• 发表日期: 2011年12期
• 关键词: chiral derivative rotation texture dopant polarized streak molar noticeable Pola

Novel isosorbide derivative containing perfluorocarbon group,bi(perfluorooctanesulfonyl)isosorbide ester as chiral dopant in liquid crystal,was synthesized.Chemical structure was characterized by elemental analysis,FT-IR,~1H NMR and ~(19)F NMR.The optical texture of the mixture was observed by polarized optical microscopy(POM).Novel chiral dopant containing perfluorocarbon group had excellent optical activity.Its specific rotation and molar rotation were noticeable higher than those of bi(4-chloromethylbenzenecarbonic)isosorbide ester.The fluorocarbon group improved the molar rotation of chiral compound and did not affect optical rotation direction.The texture of the mixture added isosorbide derivative with fluorocarbon group showed the oily streak texture.

Novel isosorbide derivative containing perfluorocarbon group, bi (perfluorooctanesulfonyl) isosorbide ester as chiral dopant in liquid crystal, was synthesized. Chemical structure was characterized by elemental analysis, FT-IR, ~ 1H NMR and ~ (19) F NMR. the mixture was observed by polarized optical microscopy (POM). Novel chiral dopant containing perfluorocarbon group had excellent optical activity. Its specific rotation and molar rotation were noticeable higher than those of bi (4-chloromethylbenzenecarbonic) isosorbide ester. The fluorocarbon group improved the molar rotation of chiral compound and did not affect optical rotation direction. The texture of the mixture added isosorbide derivative with fluorocarbon group showed the oily streak texture.