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The title complex, {[Cu2(4,4’-bipyridine)2(μ-O2CMe)2(O2CMe)2]’H2O}n 1, was synthesized and structurally characterized by X-ray crystallography. It crystallizes in monoclinic, space group C2/c with a = 13.4474(5), b = 11.7566(2), c = 19.5380(6) ’, β = 92.930(2)°, V = 3084.84(16) ’3, Z = 4, Cu2C28N4O9H30, Mr = 693.64, Dc = 1.494 g/cm3, F(000) = 1424 and μ(MoKa) = 1.436 mm-1. With the use of 2062 observed reflections (I > 2σ(I)), the structure was refined to R = 0.0769 and wR = 0.2154. In complex 1, the dimeric copper acetate units are linked through 4,4’-bipyridine to yield 1D molecular ladders. These ladders are connected via O–H···O hydrogen bonds to generate 2D layers, which are further linked through C–H···O hydrogen bonds to give a 3D supramolecular network.
The title complex, {[Cu2 (4,4’-bipyridine) 2 (μ-O2CMe) 2 (O2CMe) 2] ’H2O} n1, was synthesized and structurally characterized by X-ray crystallography. It crystallizes in monoclinic, space group C2 / c with a = 13.4474 (5), b = 11.7566 (2), c = 19.5380 (6) ’, β = 92.930 (2) °, V = 3084.84 (16)’ 3, Z = 4, Cu2C28N4O9H30, Mr = 693.64, Dc = 1.494 g / cm3, F (000) = 1424 and μ (MoKa) = 1.436 mm- 1. With the use of 2062 observed reflections (I> 2σ = 0.0769 and wR = 0.2154. In complex 1, the dimeric copper acetate units are linked through 4,4’-bipyridine to yield 1D molecular ladders. These ladders are connected via O-H · O hydrogen bonds to generate 2D layers, which are further linked through C-H ··· O hydrogen bonds to give a 3D supramolecular network.