Synthesis of 2-Aminochromene Derivatives Catalyzed by KF/Al_2O_3

来源 :Chinese Journal of Chemistry | 被引量 : 0次 | 上传用户:cainiao13939867
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A series of 2-aminochromene derivatives including 2-amino-benzochromene, 2-amino-benzochromene and 2-amino-pyrano quinolin derivatives was synthesized from aryl~aldehyde, malononitrile or ethyl cyanoacetate and 1-naphthol or 2-naphthol or 8-hydroxyquinoline in refluxing ethyl alcohol catalyzed by KF-Al 2O 3. The structures were confirmed by X-ray analysis. A series of 2-aminochromene derivatives including 2-amino-benzochromene, 2-amino-benzochromene and 2-amino-pyrano quinolin derivatives was synthesized from aryl- aldehyde, malononitrile or ethyl cyanoacetate and 1-naphthol or 2-naphthol or 8-hydroxyquinoline in refluxing ethyl alcohol catalyzed by KF-Al 2 O 3. The structures were confirmed by X-ray analysis.
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