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本文在唐敖庆及其合作者建立的配位场理论中不可约张量方法基础上,引入了准自旋群,简化了对粒子数的描述,推广了补态原理。并用这种理论分析了TbP_5O_(14)的光谱,拟合了各种参量,所得结果与实验符合得很好。
Based on the irreducible tensor method in the coordination field theory established by Tang Aoqing and his collaborators, this paper introduces quasi-spin groups, simplifies the description of the number of particles and generalizes the complement principle. The spectrum of TbP_5O_ (14) was analyzed by this theory and various parameters were fitted. The obtained results are in good agreement with the experiment.