Ti-Si-N films prepared by magnetron sputtering

来源 :稀有金属(英文版) | 被引量 : 0次 | 上传用户:tyh0713
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A film growth mechanism, expressed in terms of depositing hard films onto the soft substrate, was proposed. Multicomponent thin films of Ti-Si-N were deposited onto Al substrate with a double-target magnetron sputtering system in an Ar-N2 gas mixture. The Ti-Si-N films were investigated by characterization techniques such as X-ray diffraction (XRD), atomic force microscope (AFM), electron probe microanalyzer (EPMA), scratch test and nanoindentation. The as-deposited films have a good adhesion to Al substrate and appear with smooth and lustrous surface. The films show nanocomposite structure with nano TiN grains embedded in an amorphous SiNx matrix. The maximum hardness of the films was achieved as high as 27 Gpa. The influences of the N2 flow rate and substrate temperature on the growth rate and quality of the films were also discussed. For all samples, the Ar flow rate was maintained constant at 10 ml. min-1, while the flow rate of N2 was varied to analyze the structural changes related to chemical composition and friction coefficient. The low temperature in the deposited Ti-Si-N films favors the formation of crystalline TiN, and it leads to a lower hardness at low N2 flow rate. At the same time, the thin films deposited are all crystallized well and bonded firmly to Al substrate, with smooth and lustrous appearance and high hardness provided. The results indicate that magnetron sputtering is a promising method to deposit hard films onto soft substrate.
其他文献
目的 探讨抗凝血酶Ⅲ( AT-Ⅲ)活性在急性冠脉综合征(ACS)与稳定型心绞痛(SAP)患者之间的差别,及其在ACS患者中与术前TIMI血流级别之间的关系.方法 前瞻性纳入2011年1至6月急
猪囊尾蚴病是一种严重危害人类健康的人兽共患寄生虫病,主要流行于中非、南非、拉丁美洲、东亚和南亚等地区.采用疫苗防治该病是当前研究的热点.该文对TSOL18的编码基因、DNA
采用PCR技术获得人补体C1INH基因全长,以其为模板扩增出抗原表位基因片段命名为C1,然后将C1片段重组到pET32a(+)载体中,筛选阳性克隆,转化大肠杆菌;IPTG诱导表达,用超声波裂
The effects of microstructure change on the corrosion behaviours of Ni55Nb20Ti10Zr8Co7 bulk glass-forming alloy were investigated in 1 mol/L HCl and 0.5 mol/L H
The magnetism and work function of pure Ni(001) and Ni-Cu slab alloys were investigated using first-principles methods based on density functional theory. The c
As the huge computation and easily trapped local optimum in remanufacturing closed-loop supply chain network (RCSCN) design considered,a genetic particle swarm
The melt filling difficulty in micro cavity is one of the main challenges for micro-injection molding (MIM).An approach employing ultrasound in MIM was proposed
Hydrogenated microcrystalline silicon thin films (μc-Si:H) were deposited by plasma assistant magnetron sputtering in Ar-H2 gas mixture. The effects of growth
Ternary AlMgB thin films were synthesized on silicon (100) substrate at 573 K by radio frequency (RF) magnetron sputtering method using one Al/Mg co-target and
The optimization of network performance in a movement-assisted data gathering scheme was studied by analyzing the energy consumption of wireless sensor network