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四硫富瓦烯是一类重要的电子供体化合物,在分子导体和超分子化学领域引起广泛关注.主要介绍Cu(I)催化的叠氮和炔基的环加成反应(Cu AAC)在合成四硫富瓦烯三氮唑衍生物方面的应用进展,主要涉及含端基叠氮的四硫富瓦烯化合物和含端基炔的反应底物反应以及含端基炔的四硫富瓦烯化合物和含端基叠氮的反应底物反应两类.同时,对利用Cu AAC点击反应合成的含三氮唑功能基的四硫富瓦烯衍生物在分子识别、分子组装以及分子光电和光伏器件等光电功能材料领域的应用进展进行综述.
Tetrathiafulvalene is a kind of important electron donor compound, attracting a great deal of attention in molecular conductors and supramolecular chemistry. The introduction of Cu (I) -catalyzed cycloaddition reactions (Cu AAC) of azide and alkynyl The progress in the synthesis of tetrathiafulvalene triazole derivatives is mainly concerned with reaction of tetrazofulvalene compounds containing terminal azides and terminal alkynes and tetrathiafulvanes containing terminal alkynes Ene compounds and azide-containing reaction substrate react with two types.At the same time, the use of Cu AAC click synthesis reaction of triazole-containing tetrathiafulvalene derivatives in molecular recognition, molecular assembly and molecular optoelectronics and Photovoltaic devices and other functional materials in the field of optoelectronic applications are reviewed.