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1890年Mond等人首先分离得到Ni(CO)_4,从而开始了有机镍化学的研究。此后,1940年发现Reppe催化剂,1953年二茂镍的合成和1960年环十二碳三烯镍的分离与鉴定,都是有机镍化学发展过程中的较为重要的事情。其中,Wilke等在研究镍催化丁二烯环三聚时,分离得到了反应中间体环十二碳三烯镍,这是世界上第一个烯丙基镍型络合物。这一成就是近三十年来有机镍化学中最重要的突破。近年来,有机镍化学的发展十分迅速,据估计,已发表了上万篇研究论文,出现了一
In 1890 Mond et al first isolated Ni (CO) _4, which began the organic nickel chemistry. Since then, the discovery of the Reppe catalyst in 1940, the synthesis of nickelocene in 1953, and the isolation and characterization of the cyclododecatriene nickel in 1960 are all important issues in the development of organic nickel chemistry. Among them, Wilke, etc. in the study of nickel catalyzed butadiene ring trimerization, the reaction was isolated cyclododecatriene nickel, which is the world’s first allyl nickel complex. This achievement is the most important breakthrough in organic nickel chemistry in the last three decades. In recent years, the development of organic nickel chemistry is very rapid, it is estimated that has published tens of thousands of research papers, there has been a