Fructose derived pyridyl alcohol ligands: synthesis and application in the asymmetric diethylzinc ad

• 作 者: 周永贵 戴立信 侯雪龙
• 机 构: Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of
• 出 处: Chinese Journal of Chemistry
• 发表日期: 2000年01期
• 关键词: pyridyl aldehydes alcohol asymmetric alcohols fructose chiral optically hexane a

Easily available chiral ketones were employed for the synthesis of optically active pyridyl alcohols, which were applied in the asymmetric diethylzinc addition to aldehydes, up to 89.4% e. e. was obtained using D-fructose-derived pyridyl alcohol.

Easily available chiral ketones were employed for the synthesis of optically active pyridyl alcohols, which were applied in the asymmetric diethylzinc addition to aldehydes, up to 89.4% e. E. Was obtained using D-fructose-derived pyridyl alcohol.