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合成了甲基丙烯酸聚氧乙烯酯大分子单体,其中含有少量双端酯化的单体。大分子单体经热交联,形成交联网络型聚氧乙烯,其与硫氰化钠形成的络合物的室温电导率较同类线型聚合物高二个数量级以上(～10~(-5)Ω~(-1)cm~(-1)/298K)。红外光谱表明:交联网络含较高的非晶成份。不同络合溶剂对形成的络合物聚集态有明显影响;络合盐浓度也对络合物结晶性有影响。
Synthesis of polyoxyethylene methacrylate macromonomer, which contains a small amount of double-ended esterified monomer. The macromonomer is thermally cross-linked to form a crosslinked network of polyoxyethylene. The conductivity of the complex with sodium thiocyanate is more than two orders of magnitude higher than that of the same type of polymer (~10 ~ (-5) ) Ω ~ (-1) cm -1 / 298K). Infrared spectrum shows that the cross-linked network contains high amorphous content. Different complexing solvents have a significant effect on the aggregation state of the complex formed; the complex salt concentration also has an influence on the crystallinity of the complex.