Analysis of inhibition of concrete steel-rebar corrosion by Na_2Cr_2O_7 concentrations:Implications

来源 :Journal of Central South University | 被引量 : 0次 | 上传用户:spcheng
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Corrosion test data were measured using non-destructive electrochemical techniques and analysed for studying inhibition effectiveness by different concentrations of Na2Cr2O7 on the corrosion of concrete steel-rebar in NaCl and in H2SO4 media. For these, specifications of ASTM G16-95 R04 were combined with the normal and the Gumbel probability density functions as model analytical methods for addressing issues of conflicting reports of inhibitor effectiveness that had generated concerns. Results show that reinforced concrete samples admixed with concentrations having 4 g(0.0127 mol), 8 g(0.025 4 mol) and 6 g(0.019 1 mol) Na2Cr2O7 exhibited, in that order, high inhibition effectiveness, with respective efficiency, η, of(90.46 1.30)%,(88.41 2.24)% and(84.87 4.74)%, in the NaCl medium. These exhibit good agreements within replicates and statistical methods for the samples. Also, optimal inhibition effectiveness model in the H2SO4 medium was exhibited by 8 g(0.025 4 mol) Na2Cr2O7 concentration having η=(78.44 1.10)%. These bear implications for addressing conflicting test data in the study of effective inhibitors for mitigating steel-rebar corrosion in aggressive environments. Corrosion test data were measured using non-destructive electrochemical techniques and analyzed for studying inhibition property by different concentrations of Na2Cr2O7 on the corrosion of concrete steel-rebar in NaCl and in H2SO4 media. These are specifications of ASTM G16-95 R04 were combined with the normal and the Gumbel probability density functions as model analytical methods for addressing issues of conflicting reports of inhibitor effectiveness that had generated generated concerns. Results show that reinforced concrete samples admixed with concentrations having 4 g (0.0127 mol), 8 g (0.025 4 mol) in that order, high inhibition effectiveness, with respective efficiency, η, of (90.46 1.30)%, (88.41 2.24)% and (84.87 4.74)%, in the NaCl medium. These and 6 g (0.019 1 mol) exhibit good agreements within replicates and statistical methods for the samples. Also, optimal inhibition effectiveness model in the H2SO4 medium was exhibited by 8 g (0.025 4 mol) Na2Cr2O7 concentra tion with η = (78.44 1.10)%. These bear implications for addressing conflicting test data in the study of effective inhibitors for mitigating steel-rebar corrosion in aggressive environments.
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