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The transport coefficients of high temperature sulfur hexafluoride (SF6) plasmas in local thermodynamic equilibrium are calculated using collision integrals derived in a phenomenological approach which could be a valuable tool in the calculation of complete data sets for complex mixtures,including interactions hardly handled in the accurate multipotential methods.A systematic comparison with transport coefficients obtained using an old data set and experimental test is performed to check the reliability of the proposed approach in evaluating transport cross sections.