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本文利用“均匀表面浓度”处理法研究了微盘电极稳态电化学行为,给出了溶液中O和R均存在时可逆极化曲线的精确式,及仅有O存在时不可逆和准可逆极亿曲线的近似式。还讨论了微电极的半径与速率常数K°的测量上限之间的关系。
In this paper, the steady-state electrochemical behavior of the microdisk electrode was studied by the “uniform surface concentration” method. The exact reversible polarization curves were obtained when both O and R were present, and the irreversible and quasi-reversible polarities The approximation of the curve. The relationship between the microelectrode radius and the upper limit of the rate constant, K °, is also discussed.