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本文利用对苯二甲酰氯(TPC),对苯二胺(PPD)和亚甲基数为2和6的两种脂肪族二元胺(ADA)合成了具有不同序列结构的芳香一脂肪族共聚酰胺.研究了共聚酰胺的序列结构参数──无规度B和数均序列长度Ln与液晶临界浓度C*和中介相的类型之间的关系.
In this paper, aromatic-aliphatic copolyesters with different sequence structures were synthesized using terephthalic acid chloride (TPC), p-phenylenediamine (PPD) and two kinds of aliphatic diamines (ADA) Amide. The sequence structure parameters of copolyamide - the relationship between the randomness B and number average sequence length Ln and the type of liquid crystal critical concentration C * and the type of mesophase were investigated.