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在液镓电极上,反丁烯二腈(FDN)的电氢化二聚(EHD)不仅能在含离子型表面活性剂如四乙基对甲苯磺酸铵(TEA_PTS)溶液中发生,同样也能在含低浓度的强表面活性剂如TritonX_100溶液中进行.在不含有机表面活性剂的溶液中,FDN在滴镓电极上产生一个2电子还原波,生成名为丁二腈的饱和单体.在水溶液中加入一定浓度的TEA_PTS或低浓度的TritonX_100时,原来的2电子还原波分裂成两个连续的单电子还原波,生成相应的电氢化二聚物.
Electrokinetic dimerization (EHD) of fumaronitrile (FDN) on liquid gallium electrodes can occur not only in solutions containing ionic surfactants such as tetraethyl ammonium p-toluene sulfonate (TEA_PTS), but also In a low concentration of a strong surfactant such as Tri tonX_100 solution. In solutions that do not contain organic surfactants, FDN generates a 2-electron reduction at the gallium-donning electrode, producing a saturated monomer called succinonitrile. When a certain concentration of TEA_PTS or low concentration of TritonX_100 is added to the aqueous solution, the original two-electron reduction wave splits into two successive single-electron reduction waves to generate the corresponding hydro-hydrogenated dimer.