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Compound [V_ 16 O_ 38 (Cl)][Cu(enMe)_2]_ 3.5 ·2H_2O(1) has been hydrothermally synthesized and characterized by means of single-crystal X-ray diffraction,elemental analysis,IR,EPR and TGA analysis. The X-ray crystallography shows that compound 1 contains a new {V_ 16 O_ 38 } cluster shell,which is connected by [Cu(enMe)_2] 2+ coordination fragments into a 3-D framework. The compound crystallized in a monoclinic system with space group P2(1)/n,M =2235.82,a =1.26076(3) nm,b =2.55802(6) nm,c =2.14742(4) nm,β =90.7380(10)°, V =6.9250(3) nm 3,Z =4,F (000)=4418,D _c=2.145 g·cm -3 , μ =3.227 mm -1 ,( Δ/σ )=0.000,S =1.066.
Compound [V_16O_38 (Cl)] [Cu (enMe) _2] _3.5_2O_ (1) has been hydrothermally synthesized and characterized by means of single-crystal X-ray diffraction, elemental analysis, IR, EPR and TGA analysis The X-ray crystallography shows that compound 1 contains a new {V_16O_38} cluster shell, which is connected by [Cu (enMe) _2] 2+ coordination fragments into a 3-D framework. The compound crystallized in a monoclinic system with space group P2 (1) / n, M = 2235.82, a = 1.26076 (3) nm, b = 2.55802 (6) nm, c = 2.14742 (4) nm, β = 90.7380 (3) nm 3, Z = 4, F (000) = 4418, D c = 2.145 g · cm -3, μ = 3.227 mm -1, (Δ / σ) = 0.000, S = 1.066.