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A new dinuclear copper(II) complex ([Cu(C12H17N2O)(N3)]2, C24H34Cu2N10O2) has been synthesized and characterized by X-ray structure determination. It crystallizes in the monoclinic system, space group P21/c with a = 18.529(4), b = 10.933(2), c = 14.534(3) ?, β = 111.07(3)°, V = 2748(1) ?3, Z = 4, Mr = 621.69, F(000) = 1288, Dc = 1.503 g/cm3 and μ(MoKα) = 1.590 mm?1. The structure was refined to R = 0.0647 and wR = 0.1846 for 4406 observed reflections (I > 2σ(I)). The asymmetric unit comprises two halfmolecules. The complex is a centrosymmetric dimmer in which the copper atoms are penta-coordinated by three coordination atoms from the corresponding tridentate Schiff base ligand and two bridging azide anions. The Cu(II)…Cu(II) average distance is 3.350(1) ?.
It crystallizes in the monoclinic system, space group P21 / c with a = 18.529 (C12H17N2O) (N3)] 2, C24H34Cu2N10O2) has been synthesized and characterized by X- B = 10.933 (2), c = 14.534 (3)?, Β = 111.07 (3) °, V = 2748 (1)? 3, Z = 4, Mr = 621.69, F (000) = 1288 , Dc = 1.503 g / cm3 and μ (MoKα) = 1.590 mm -1. The structure was refined to R = 0.0647 and wR = 0.1846 for 4406 observed reflections (I> 2σ (I)). The complex is a centrosymmetric dimmer in which the copper atoms are penta-coordinated by three coordination atoms from the corresponding tridentate Schiff base ligand and two bridging azide anions. The Cu (II) ... Cu (II) .