Syntheses and Structures of Three Hybrid Materials Using Vanadium Polyoxoanions and Macrocyclic Copp

• 作 者: 欧光川 廖阳 向岳峰 袁先友 李治章
• 机 构: Key Laboratory of Comprehensive Utilization of Advantage Plants Resources in Hunan South/Department
• 出 处: 结构化学
• 发表日期: 2017年01期
• 关键词: reactant vanadium diverse coordinated Blocks rings inorganic bridges heating com

The reactions of the four-coordinated macrocyclic copper complex [CuL](ClO_4)_2(L = 1,4,8,11-tetraazacyclotetradecane) with NH_4VO_3 under different conditions gave three inorganic-organic hybrid materials of [CuL][VO_3]_2·2.33H_2O(1), [CuL]_3[V_(10)O_(28)]·8H_2O(2) and [Cu L]3[V_6O_(18)]·8H_2O(3). Single-crystal X-ray diffraction analyses reveal that three diverse vanadium polyoxoanions, [V_6O_(18)]6- ring, [V_(10)O_(28)]6- cluster, and [V_(12)O_(35)]~(10-) ring, were isolated from the same reactant NH_4VO_3 under different conditions. The [CuL]~(2+) bridges the [V10O28]6- clusters to form a two-dimensional sheet in 2, and link the [V_6O_(18)]~(6-) rings in 1 and [V_(12)O_(35)]~(10-) rings in 3 into three-dimensional frameworks, respectively.

The reactions of the four-coordinated macrocyclic copper complex [CuL] (ClO_4) _2 (L = 1,4,8,11-tetraazacyclotetradecane) with NH_4VO_3 under different conditions gave three inorganic-organic hybrid materials of [CuL] [VO_3] _2 · 2.33H2O (1), [CuL] _3 [V_ (10) O_ (28)] · 8H_2O and [CuL] 3 [V_6O_ (18)] · 8H_2O (10) O (28)] 6-cluster, [V_ (12) O_ (35)] ~ (10-) ring diffraction analysis reveals that three diverse vanadium polyoxoanions [V_6O_ , were isolated from the same reactant NH_4VO_3 under different conditions. [CuL] ~ (2+) bridges the [V10O28] 6-clusters to form a two-dimensional sheet in 2, and link the [V_6O_ (18) 6) rings in 1 and [V_ (12) O_ (35)] ~ (10-) rings in 3 into three-dimensional frameworks, respectively.