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我们曾利用场论的Noether定理导出点称守恒原理并借以讨论化学反应与光谱跃迁等过程的选择规则。为讨论σ迁移反应的对称性问题又引入了反应反演reaction-reversal变换及其联合点称的对称性。本文将利用反应反演联合点称的对称性来分析歧化反应的立体化学特征。
We have used Noether’s theorem of field theory to derive the principle of conservation of points and discuss the selection rules of chemical reactions and spectral transitions. In order to discuss the symmetry of the σ migration reaction, the symmetry of the reaction inversion reaction-reversal transform and its joint point is also introduced. In this paper, we will use the symmetry of the joint inversion of reaction inversion to analyze the stereochemical characteristics of the disproportionation reaction.