【摘 要】
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A new hetero-six-nuclear cluster was synthesized and determined by X-ray diffraction technique. The four-carboxylate groups are bound to the Cu(II) atoms to for
【出 处】
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Chinese Chemical Letters
论文部分内容阅读
A new hetero-six-nuclear cluster was synthesized and determined by X-ray diffraction technique. The four-carboxylate groups are bound to the Cu(II) atoms to form Cu(OR)4Cu paddle-wheel-type cage between two DMF as the basis for the cluster. The distance of two copper(II) atoms is 2.642 ?, and they are bridged by the carboxylate groups. A huge system plane was auto-assembled by four host molecules and two Cu (II) ions, which was observed in the crystal structure.
A new hetero-six-nuclear cluster was synthesized and determined by X-ray diffraction technique. The four-carboxylate groups are bound to the Cu (II) atoms to form Cu (OR) 4Cu paddle-wheel- the basis for the cluster. The distance of two copper (II) atoms is 2.642 ?, and they are bridged by the carboxylate groups. A huge system plane was auto-assembled by four host molecules and two Cu (II) ions, which was observed in the crystal structure.
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