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运用金属外层d电子的存在对Pauling电负性修正,可得到与实验值较好吻合的氢在金属电极表面的吸附热计算值。氢电极反应由于其在电化学生产实践中的重要地位及电化学理论研究中的独特作用,长期来受到了理论工作者和实际工作者的重视。
By using the existence of d outer electrons on Pauling electronegativity, we can get the calculated value of hydrogen adsorption on the surface of metal electrode which is in good agreement with the experimental data. Hydrogen electrode reaction has long been valued by both theoreticians and practitioners because of its important role in electrochemical production practice and the unique role of electrochemical theory.