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研究了CH3N3在第一电子吸收带的光解,获得了生成三线态CH3N自由基的重要证据并对可能的反应机制进行了讨论.其机理以激发态CH3N3经单线态三线态相互作用后解离生成三线态自由基的可能性较大.
The photodissociation of CH3N3 in the first electron absorption band was studied. The important evidence for generating CH3N radicals was obtained and the possible reaction mechanism was discussed. The mechanism of the excited state CH3N3 through the singlet triplet state after the dissociation of the possibility of generating triplet radical is more likely.