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选取1,9—二(2—氟代苯基)—2,5,8—三氮杂壬烷与铜(Ⅱ)的苯甲酸盐和硝酸盐,合成了两个新的配合物[Cu(C18H23F2N3)(C7H5O2)(H2O)](C7H5O2)·2(H2O)(1)和[Cu(C18H23F2N3)(NO3)2]·(H2O)1/2(2),并获得其单晶,测定了晶体结构.单晶衍射数据显示化合物(1)属三斜晶系Pi空间群,化合物(2)属单斜晶系Cc空间群
Two benzoic acid salts and nitrates of 1, 9-bis (2-fluorophenyl) -2,5,8-triazononane and copper (Ⅱ) were synthesized and two new complexes [Cu (C18H23F2N3) (C7H5O2) (H2O)] (C7H5O2) · 2 (H2O) (1) and [Cu (C18H23F2N3) (NO3) 2] · (H2O) 1/2 (1) belongs to the triclinic Pi space group, while the compound (2) belongs to the monoclinic Cc space group