Growth Mechanism and Characterization of ZnO 3D Nanocrystals by Laser Irradiation & Coaxially Transp

来源 :Journal of Wuhan University of Technology(Materials Science | 被引量 : 0次 | 上传用户:xingxing7978
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Different three-dimension (3D) nanotetrapods,containing club-like nanocrystals,nanotetrapods and four-foot-like nanocrystals were synthesized from Zinc sheet via CO2 laser irra-diation and coaxially transporting O2.Different nanoproducts were fabricated by changing the content of oxygen in the experiment.The morphologies,components,phase structures and optical properties of the products were investigated by a field-emission scanning electron microscopy,an X-ray diffraction,an energy dispersed X-ray spectrometer and a photoluminescence spectroscope.The X-ray diffraction spectra were obtained on a Rigaku D/max 2500PC diffractometer.The ex-perimental results reveal that high quality ZnO nanotetrapods can be fabricated on the special pa-rameters,and growth of ZnO nanotetrapods depends on Vapour-Liquid-Solid(VLS) model,and the content of oxygen in the gas,namely,oxygen partial pressure is one of main factors to control morphologies and optical properties of ZnO nanotetrapods; these advantages above are important for realization of optoelectronic devices. Different three-dimension (3D) nanotetrapods, containing club-like nanocrystals, nanotetrapods and four-foot-like nanocrystals were synthesized from Zinc sheet via CO2 laser irra-diation and coaxially transported O2.Different nanoproducts were fabricated by changing the content of oxygen in the experiment. morphologies, components, phase structures and optical properties of the products were investigated by a field-emission scanning electron microscopy, an X-ray diffraction, an energy dispersed X-ray spectrometer and a photoluminescence spectroscope. X-ray diffraction spectra were obtained on a Rigaku D / max 2500PC diffractometer. The ex-perimental results reveal that high quality ZnO nanotetrapods can be fabricated on the special pa-rameters, and growth of ZnO nanotetrapods depends on Vapor-Liquid-Solid (VLS) model, and the content of oxygen in the gas, namely, oxygen partial pressure is one of main factors to control morphologies and optical properties of ZnO nanotetrapods; these advantagags es above are important for realization of optoelectronic devices.
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