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美国阿冈国家实验室的J.R.Miller和芝加哥大学的G.L.Closs最近在研究分子内的电子转移过程时,证明了30多年前R.A.Marcus教授在研究电子转移理论时所预测的“逆转区”(Inverted Region)的存在。一般说来愈是放热的反应进行得愈快,而在所谓“逆转区”却与此相反:反应放热性增加,反应速率却下降。Marcus的这一推测与经典的研究相矛盾,而且多年来得不到实验的证明。Miller认为
JR Miller of the Argonne National Laboratory in the United States and GLCloss of the University of Chicago recently studied the intramolecular electron transfer process and demonstrated that the Inverted Region predicted by Professor RAMarcus more than 30 years ago when studying electron transfer theory )The presence. In general, the more exothermic reactions proceed faster, whereas in the so-called “reversal zone” the opposite is true: the exothermicity of the reaction increases and the rate of reaction decreases. This speculation by Marcus contradicts classic research and has not been experimentally proven for years. Miller thinks