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旋光性有机化合物的过渡金属配合物在生命现象中占有重要的地他.标题配合物是为此目的而研究的系列配合物之一.按照文献方法合成得到有旋光性质的 Schiff 碱N-(5-氯-邻羟基苯亚甲基)-α-苯乙胺,再与氯化钯反应得到粗产品,用乙醇-氯仿混合溶剂重结晶分别得到桔红色的 R、S 型标题产物.
The transition metal complexes of optically active organic compounds occupy an important position in life phenomena. The title complex is one of a series of complexes studied for this purpose. The optically active Schiff base N- (5 -chloro-o-hydroxybenzylidene) -α-phenylethylamine, and then reacted with palladium chloride to obtain a crude product, which was recrystallized from an ethanol-chloroform mixed solvent to obtain the orange-red R and S-type title products, respectively.