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近年来,由于对大气化学、反应动力学的机理探索,使对含惰性原子的离子簇合物的研究受到重视.对离子簇合物N_2~+He和N_2~+Ne等进行了电子光谱、红外光谱以及理论方面的研究.在这两个离子簇合物中,N_2~+与HeNe的作用很弱,其中的N_2~+基本保持孤立N_2~+离子的特性.Ar原子比He和Ne原子的极化率大,可变性大.可以想见,在(N_2Ar)~+中N_2~+与Ar作用更强,实际上已具有化学键的性质.本文的研究着重于体系(N_2Ar)~+的势能面,有关(N_2Ar)~+的实验研究亦在开展中.
In recent years, due to the exploration of the mechanism of atmospheric chemistry and reaction kinetics, attention has been paid to the study of ionic clusters with inert atoms. The electronic spectra of ionic clusters N_2 ~ + He and N_2 ~ + Ne, Infrared spectroscopy and theoretical studies.In these two clusters, the effect of N 2 ~ + on HeNe is very weak, among them N_2 ~ + basically maintains the characteristics of isolated N_2 ~ + ions.Ar atomic ratio He and Ne atoms (N_2Ar) ~ +, N_2 ~ + has a stronger interaction with Ar, and actually has the chemical bond property.In this paper, the research focuses on the potential energy of the system (N_2Ar) ~ + Surface, the (N_2Ar) ~ + experimental research is also underway.