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聚甲亚胺(PAM)作为一类新的有机导电聚合物而引起人们的关注.其在航天技术中、能量储存和转换器件、电池正负极、半导体材料等方面有着广泛的应用前景.最近,人们选择有效的合成方法,得到多种不同结构的聚甲亚胺高聚物:+R—HC=N—R~1—N=CH为其中典型的一类,它的实验电导率已超过10~(-2)Q~(-1)·cm~(-1).杂原子在主共轭链上的引入,不仅增加了高分子结构的多样性,同时也将改变原高聚物的部分性能(如可溶性、空气稳定性等),
As a new class of organic conductive polymers, polymethyl imine (PAM) attracts the attention of people, and it has a wide range of applications in aerospace technology, such as energy storage and conversion devices, positive and negative electrodes of batteries, semiconductors, etc. Recently, , People choose effective synthesis method to get a variety of different structures of polymethyleneimine polymer: + R-HC = N-R ~ 1-N = CH is one of the typical class, its experimental conductivity has exceeded 10 ~ (-2) Q ~ (-1) · cm ~ (-1) .The introduction of heteroatoms into the main conjugate chain not only increases the diversity of polymer structure, but also changes the Some properties (such as solubility, air stability, etc.),