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以非活化烯烃为底物,利用(-)-sparteine诱导的分子间-分子内不对称碳锂化反应构建高区域选择性和立体选择性的碳碳新键,合成了一系列手性化合物.综述了近十几年基于(-)-sparteine的不对称碳锂化反应最新研究成果.
A series of chiral compounds were synthesized by using (-) - sparteine-induced asymmetric carbonylation of (-) - sparteine to construct highly selective and stereoselective carbon-carbon bonds. The recent research results of asymmetric carbon lithiation based on (-) - sparteine in recent ten years are summarized.