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一种Cu(II)超分子配合物[Cu(μ1,5-dca)(dca)(bpy)]n(1)被合成并用单晶X-射线和磁性进行了表征.化合物1是由两组平行的二维网互相穿插形成的三维结构.磁表征结果显示在化合物1中Cu离子之间表现出通过二氰胺和4,4′-联吡啶桥传递的弱反铁磁相互作用.
A Cu (II) supramolecular complex [Cu (μ1,5-dca) (dca) (bpy)] n (1) was synthesized and characterized by single crystal X-ray and magnetic properties. Compound 1 consisted of two groups The parallel two-dimensional network interspersed with each other to form a three-dimensional structure.Magnetic characterization results showed that Cu ions in compound 1 showed weak anti-ferromagnetic interactions through the dicyanamide and 4,4’-bipyridine bridges.