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波聚合是一种通过局部反应区域向未反应区域连续移动将单体转化为聚合物的反应模式,具有简便快速、节能降耗和产物性能优异等优势,是化学合成、功能材料与结构材料制备的新方法。本文对波聚合反应体系、引发、过程、应用及存在问题等方面进行综述。重点评述了新型波聚合体系如二元或多元体系、离子液体体系、深共晶溶剂体系等;新型引发剂如光引发剂和离子液体引发剂等特殊引发剂;波聚合反应体系中的助剂如填料、交联剂、链转移剂、活化剂、增稠剂、表面活性剂和催化剂等对聚合过程和产物结构性能的影响;新发展的引发方式如紫外线、水、等离子体和耦合引发等;以及特殊波聚合过程。最后,展望了波聚合存在问题和商业化应用的研究方向。
Wave polymerization is a reaction mode which transforms monomer to polymer through continuous reaction of local reaction region to unreacted region. It has the advantages of simple, rapid, energy saving and excellent product performance. It is a kind of chemical synthesis, functional material and structural material preparation The new method This article reviews the wave polymerization system, initiation, process, application and existing problems. The new wave polymerization systems such as binary or multiple systems, ionic liquid systems, deep eutectic solvent system and so on are reviewed. Special initiators such as photoinitiators and ionic liquid initiators are introduced. Auxiliary agents in wave polymerization system Such as fillers, crosslinking agents, chain transfer agents, activators, thickeners, surfactants and catalysts on the polymerization process and product structure properties; newly developed initiation methods such as UV, water, plasma and coupling initiation ; And special wave polymerization process. Finally, the research direction of the existence and commercial application of wave polymerization is prospected.