论文部分内容阅读
研究了Cd2+掺杂的ZnS纳米晶的光致发光特性,结果表明,当Cd的掺杂量较低时(≤5%,摩尔分数);ZnS纳米晶试样的荧光强度显著提高,Cd的掺杂量为0.5%时,掺杂试佯的相对荧光强度约为未掺杂试样的5倍,发射光谱明显宽化随着Cd含量的提高,试样的激发光谱(350nm→488nm)和发射光谱(由蓝→绿→红)红移,当Cd含量≥5%时,其发射光谱与CdS纳米晶一致,但荧光强度比Cds纳米晶高.XRD分析显示,掺杂试样的晶格结构由Cd的掺杂量决定.
The photoluminescence (PL) characteristics of CdS-doped ZnS nanocrystals were studied. The results showed that the fluorescence intensity of ZnS nanocrystalline samples increased significantly when the doping amount of Cd was lower than 5% (molar fraction) When the impurity amount is 0.5%, the relative fluorescence intensity of the doped sample is about 5 times that of the undoped sample, and the emission spectrum is obviously broadened. With the increase of Cd content, the excitation spectrum (350nm → 488nm) And emission spectra (from blue → green → red). When the content of Cd is more than 5%, the emission spectrum is consistent with that of CdS nanocrystals, but the fluorescence intensity is higher than that of Cds nanocrystals. XRD analysis shows that the lattice structure of the doped sample is determined by the doping amount of Cd.