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合成了４种氮氧自由基桥联的五氟丙酸镍双核配合物［Ｎｉ（ｐｆｐｒ）＿２］＿２ＮＩＴＲ·ｎＨ＿２Ｏ．对该配合物进行了元素分析和热重－差热分析，测定了红外光谱、紫外－可见光谱、电子顺磁共振和摩尔电导．讨论了配合物的结构，测量了［Ｎｉ（ｐｆｐｒ）＿２］＿２ＮＩＴＰｈＣｌ·４Ｈ＿２Ｏ和［Ｎｉ（ｐｆｐｒ）＿２］＿２ＮＩＴＰｈＯＭｅ·４Ｈ２Ｏ的变温磁化率（４～３００Ｋ），表明配合物具有非正规自旋态的Ｎｉ（Ⅱ）－Ｃｕ（Ⅱ）－Ｎｉ（Ⅱ）三核体系的磁行为．通过与理论公式拟合，得到交换积分Ｊ值分别为－１５２．８ｃｍ￣（－１）和－１７４．６ｃｍ￣（－１），表明镍－自由基－镍之间有较强的反铁磁相互作用．
Four kinds of Ni (pfpr) _2] _2NITR · nH_2O were synthesized by nitrogen-oxygen free radical bridged nickel pentafluoropropionate. The complex was characterized by elemental analysis and TG-DTA, and the IR, UV-Vis, EPR and molar conductance were measured. The structures of the complexes were discussed. The temperature-dependent magnetic susceptibility (4 ~ 300K) of [Ni (pfpr) _2] _2NITPhCl · 4H_2O and [Ni (pfpr) _2] _2NITPhOMe · 4H2O were measured. Magnetic Behavior of Ni (Ⅱ) -Cu (Ⅱ) -Ni (Ⅱ) Trinuclear System. By fitting with the theoretical formula, the exchange integral J values were -152.8 cm -1 and -174.6 cm -1, respectively, indicating strong antiferromagnetic interaction between Ni-free-nickel interaction.