论文部分内容阅读
将三价铑离子配合物用于催化甲亚胺内盐与取代的丙烯酰胺之间的氧化偶联反应,实现了三取代的吡唑化合物的合成.在这个过程中,取代的丙烯酰胺的烯烃发生了C–H键活化.此类反应和用丙烯酸酯时的反应具有不同的选择性.
The trivalent rhodium ion complex is used to catalyze the oxidative coupling reaction between the imine salt and the substituted acrylamide to achieve the synthesis of trisubstituted pyrazole compounds.In this process, the substituted acrylamide olefin The C-H bond activation occurs. Such reactions have different selectivities than the acrylate reaction.