论文部分内容阅读
报导了一种带5’-CO2Me取代基的螺嗪(A)的开环形式(B)与金属离子的配合作用,利用紫外可见吸收光谱研究了金属离子浓度的影响,并证明了有色体配合物(C)的主要消色过程是先解离出金属离子生成(B).再褪色生成闭环无色体(A).未观测到由(C)直接褪色生成(A)的过程·
Reported the complexation of an open-ring form (B) of a spiroazine (A) with a 5’-CO 2 Me substituent with a metal ion. The influence of the metal ion concentration was investigated by UV-visible absorption spectroscopy and it was demonstrated that the colorimetric coordination The main achromatic process of (C) is the dissociation of metal ions (B). Re-fading to generate closed-loop color bodies (A). The process of (A) direct discoloration by (C) was not observed