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含有表面活性剂的多元络合物体系已在分析化学中普遍应用。从报道看应用的工作多于理论方面的探讨。假若能从体系各组分的相互作用着手,对络合物的状态、形成机理、反应过程的热力学及动力学等逐一讨论,会有助于寻求满意的体系及提高多元络合物的分析性能。本文研究了表面活性剂对有机试剂缔合状态的影响。结果表明,各种类型的表面活性剂均能促使有机试剂解缔,提高其反应活性,由此可得到新的启发,思考一些理论及实验中所遇到的问题。
Multicomponent complex systems containing surfactants have found widespread use in analytical chemistry. From the report to see the application of more than theoretical aspects of the work. If we can start with the interaction of the various components of the system, one by one to discuss the state of the complex, formation mechanism, thermodynamics and kinetics of the reaction process will help to find a satisfactory system and improve the analytical performance of the multi-complex . This article studies the effect of surfactants on the association of organic reagents. The results show that all kinds of surfactants can promote the dissociation of organic reagents and enhance their reactivity, which can be a new inspiration, think about some theoretical and experimental problems encountered.