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测定了尿素—LiCl、尿素—NaCl、尿素—kCl、尿素—CuCl_2、尿素—NiCl_2、尿素—NaCl—CuCl_2、尿素—NaCl—NiCl_2熔体的电导率,研究了温度、浓度、碱金属离子大小对电导的影响。在所研究的温度范围内(100~136℃),上述体系的电导率与温度成直线关系,尿素一碱金属氯化物熔体的电导率随阳离子半径增大而减少,且与阳离子半径平方的倒数成线性关系。尿素—CuCl_2(0.1~1.0mol·dm ̄(-3))的电导率在0.8mol·dm ̄(-3)附近出现最高点,在0.74mol·dm ̄(-3)氯化物浓度附近,摩尔电导的顺序是LiCl>NaCl>KCl>。
The conductivity of urea-NiCl, urea-kCl, urea-CuCl_2, urea-NiCl_2, urea-NaCl-CuCl_2 and urea-NaCl-NiCl_2 melt were measured and the effects of temperature, The effect of conductance. In the studied temperature range (100 ~ 136 ℃), the conductivity of the above system has a linear relationship with the temperature. The conductivity of the urea-alkali metal chloride melt decreases with the increase of the cation radius, and is proportional to the square of the cation radius Countdown into a linear relationship. The conductivity of urea-CuCl_2 (0.1-1.0 mol · dm -3) appeared the highest point around 0.8 mol · dm -3, and at 0.74 mol · dm -3 of chlorine Near the chemical concentration, the order of molar conductance is LiCl> NaCl> KCl>.