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近年来,四硫富瓦烯(Tetrathiafulvalene,TTF)衍生物的设计合成、超分子组装、组装材料的物理性能研究及其在有机电子器件中的应用引起了人们广泛的研究兴趣。在本文中,我们简略综述硫原子桥联芳基取代/稠合四硫富瓦烯衍生物(Ar-S-TTF)的最新研究进展,包括其高效合成、电化学及光学性能研究、分子的结构特征/空间堆积方式,以及此类分子与球形原子簇(富勒烯、杂多酸)之间的超分子组装及组装材料的性能。
In recent years, the design and synthesis of tetrathiafulvalene (TTF) derivatives, supramolecular assembly, the physical properties of assembled materials and their applications in organic electronic devices have attracted a great deal of research interest. In this paper, we briefly review the recent progress in sulfur-atom bridged arylsubstituted / fused tetrathiafulvalene derivatives (Ar-S-TTF), including its high-performance synthesis, electrochemical and optical properties, molecular Structural features / spatial packing patterns, and the properties of supramolecular assembly and assembly of such molecules with spherical clusters of atoms (fullerenes, heteropolyacids).