Preparation of （ R ）- and （ S ）-2-Allyl-1,3,2-Dinaphtho （α,β）[d. f]dioxaborepin and Their Reactions

• 作 者: LiuDe-jun ShanZi-xing WangGuo-
• 机 构: CollegeofChemistryandMolecularSciences
• 出 处: 武汉大学学报：自然科学英文版
• 发表日期: 2003年04A期
• 关键词: 乙醛 烯丙基 温度 CH2CL2
• 基金项目: 国家自然科学基金

(R)- and (S)-2-Allyl-1,3,2-dinaphtho(α,β)[d.f]dioxaborepin ((R)-2 and (S)-2) have been first prepared by the reaction of (R)-(+)- or (S)-(-)-1,1′-bi-2-naphthol and triallylborane in THF at room temperature, respectively. (S)-2 and (R)-2 are sensitive to m