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Based on synthesizing pure spinel type lithium manganese oxides, the derivations such as LiMn1. 5 Ti0. 5-O4, LiMn1.5 Fe0. 5 O4, LiMn1.5 Ni0.5 O4 and LiMn1.5 Zn0. 5 O4 were prepared using solid-step-sintering method. The structures were characterized by us