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利用四苯硼酸铷（ＲｂＢＰｈ４）在纯水及直链一元醇中的溶解度数据，计算了ＲｂＢＰｈ４在纯水及直链一元醇中缔合常数、活度系数及缔合度．将缔合常数与实验温度线性回归求得ＲｂＢＰｈ４在纯水及醇溶剂中的缔合热力学函数．应用Ｂｏｒｎ静电相互作用理论对缔合热力学函数的变化规律进行讨论．
Using the solubility data of RbBPh4 in pure water and linear monohydric alcohol, the association constant, activity coefficient and association degree of RbBPh4 in pure water and linear monohydric alcohol were calculated. The association thermodynamic function of RbBPh4 in pure water and alcohol solvent was obtained by linear regression of association constant and experimental temperature. The Born electrostatic interaction theory is used to discuss the change rule of the association thermodynamic function.