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A novel complex, (H 3O) 2[Ni(2,6-pydc) 2]·2H 2O was synthesized in an aqueous solution and characterized by means of single-crystal X-ray diffraction, elemental analyses and IR spectra. The X-ray structural analysis revealed that the novel compound forms three-dimensional(3D) networks by both π-π stacking and hydrogen-bonding interactions. The crystal data for the complex are a=13.853(3) nm, b=9.6892(19) nm, c=13.732(3) nm, α=90.00°, β=115.52(3)°, γ=90.00°, Z=3, R 1=0.0786, wR 2=0.1522.
A novel complex, (H 3O) 2 [Ni (2,6-pydc) 2] · 2H 2O was synthesized in an aqueous solution and characterized by means of single-crystal X-ray diffraction, elemental analyzes and IR spectra. The X -ray structural analysis revealed that the novel compound forms three-dimensional (3D) networks by both π-π stacking and hydrogen-bonding interactions. The crystal data for the complex are a = 13.853 (3) nm, b = 9.6892 (19) nm, c = 13.732 (3) nm, α = 90.00 °, β = 115.52 (3) °, γ = 90.00 °, Z = 3, R 1 = 0.0786, wR 2 = 0.1522.