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1968年,Fuchs等首次用控制水解法从WO(CH_3)_4中获得了六聚钨酸盐,它的阴离子W_6O_(19)~(2-)结构也已被测定。迄今六钨酸盐主要还是局限于几个多碳有机胺盐。以粉状白钨酸为原料,在二甲基亚砜(DMSO)中制得了一系列DMSO配位的多价金属的六钨酸盐晶体,并测定了其中部分盐类的晶体结构。但六聚钨酸仍未
In 1968, for the first time, Fuchs et al. Obtained hexametungstate from WO (CH_3) _4 by controlled hydrolysis. The structure of its anion W_6O_ (19) ~ (2-) has also been determined. To date, six tungstates are mainly limited to several carbon organic amine salts. A series of DMSO-coordinated polyvalent metal hexatotungstate crystals were prepared from powdered tungstosilicic acid in dimethylsulfoxide (DMSO). The crystal structures of some of the salts were determined. However, hexa-tungstic acid has not yet