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The reaction of [Et4N]2[Mo2(SC6H11)2(CO)8] and I2 in MeCN affords a new dinu- clear molybdenum(I) complex [Mo2(SC6H11)2(CO)6(CH3CN)2] 1 (Mr = 672.46). The crystal and molecular structures have been determined by X-ray single-crystal diffraction. 1 crystallizes in monoclinic, space group P21/c with a = 9.302(1), b = 15.514(2), c = 9.307(1) ?, β = 92.979(2)o, V = 1341.4(3) ?3, Z = 2, Dc = 1.665 g/cm3, μ = 11.28 cm-1, F(000) = 676, R = 0.0461 and wR = 0.1274 for 1702 observed reflections with I > 2σ(I). 1 possesses a rhombic bimetallic core MoS2Mo with the Mo–Mo bond length of 2.9712(4) ? and Mo–S of 2.4821(5) ?.
The reaction of [Et4N] 2 [Mo2 (SC6H11) 2 (CO) 8] and I2 in MeCN affords a new dinu- clear molybdenum (I) complex [Mo2 (SC6H11) 2 (CO) 6 (CH3CN) 2] Mr = 672.46). The crystal and molecular structures have been determined by X-ray single-crystal diffraction. 1 crystallizes in monoclinic space group P21 / c with a = 9.302 (1), b = 15.514 (1), β = 92.979 (2) o, V = 1341.4 (3)? 3, Z = 2, Dc = 1.665 g / cm3, μ = 11.28 cm-1, F and wR = 0.1274 for 1702 observed reflections with I> 2σ (I). 1 possesses a rhombic bimetallic core MoS2Mo with the Mo-Mo bond length of 2.9712 (4)? and Mo-S of 2.4821 (5) ?.