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一、OXO反应是一碳化学的重要组成部份由于石油和天然气的短缺,化学界关切地注视着一碳化学作为潜在的能源和化工原料的开发研究。一碳化学主要由费-托合成,甲醇制备及甲醇化学、一氧化碳加氢、甲烷化、羰基化及“OXO反应”等六部份组成。1938年德国鲁尔化学公司的O·Roelen发现,在钴作催化剂的费-托合成反应中,烯烃与一氧化碳和氢发生作用生成比原料烯烃多一个碳原子的醛和醇的产物,被认为是在烯烃双键上加入一个甲醛(H—CHO)的
First, the OXO reaction is an important part of the carbon chemistry Due to the shortage of oil and natural gas, the chemical community is concerned about the development of one-carbon chemistry as a potential energy and chemical raw material. One-carbon chemistry is mainly composed of six parts: Fischer-Tropsch synthesis, methanol preparation and methanol chemistry, carbon monoxide hydrogenation, methanation, carbonylation and “OXO reaction ”. O. Roelen of the German company Ruhr Chemie in 1938 found that in the Fischer-Tropsch synthesis of cobalt as a catalyst the reaction of olefins with carbon monoxide and hydrogen produces aldehydes and alcohols one more carbon than the starting olefins and is considered to be Add a formaldehyde (H-CHO) to the olefinic double bond