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在三乙胺存在下,四氟乙烯五聚体(1)与醇反应生成2-烷氧基全氟-4-乙基-3,4-二甲基己烯-[2](2),与醇钠发生S_N2′反应,生成2-(1′-烷氧基四氟乙基)-全氟-3-甲基-3-乙基戊烯-[1](3).3在三乙胺作用下,发生重排得到化合物2.3进一步与醇钠反应生成酰氟4和二烷氧基取代物5.4在室温下对碱稳定,它不易与醇发生酯化反应,与醇钠回流才生成酯6.1在丙酮中被高锰酸钾氧化成3-氢全氟2-甲基戊烷(8),后者与丙酮生成等分子络合物.
Tetrafluoroethylene pentamer (1) reacts with alcohol in the presence of triethylamine to give 2-alkoxyperfluoro-4-ethyl-3,4-dimethylhexene- [2] S_N2 ’reacted with sodium alkoxide to form 2- (1’-alkoxytetrafluoroethyl) -perfluoro-3-methyl-3-ethylpentene- [1] Amine function, the rearrangement to give compound 2.3 further reaction with the sodium alcoholate 4 and dialkyl alkoxy substituted 5.4 stable at room temperature alkali, it is not easy with the esterification of alcohol, with the sodium alkoxide back to generate ester 6.1 Oxidation of potassium permanganate to 3-hydroperfluoro-2-methylpentane (8) in acetone, which forms an equi-complex with acetone.