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本文采用水热法合成了一个新的金属有机-无机杂化化合物[Cu4(phen)4(HPO4)2(H2O)2(OH)2][HPMo12O40]·H2O(1)(phen=邻菲咯啉)。通过元素分析、红外光谱、热重分析、X-射线单晶衍射对其进行了结构表征。化合物1是由四核铜磷酸盐、Keggin阴离子和晶格水分子组成。四核铜磷酸盐和多阴离子之间通过弱的M…O相互作用形成二维结构(M=Cu,Mo),该二维结构通过氢键和π-π相互作用形成三维超分子框架,还对化合物1的电化学和电催化性质进行了研究。
In this paper, a new metal-organic hybrid compound [Cu4 (phen) 4 (HPO4) 2 (H2O) 2 (OH) 2] [HPMo12O40] · H2O Morpholine). The structure was characterized by elemental analysis, IR, TG, X-ray single crystal diffraction. Compound 1 is composed of tetranuclear copper phosphates, Keggin anions and lattice water molecules. Tetra-nuclear copper phosphate and polyanions form a two-dimensional structure (M = Cu, Mo) by a weak M ... O interaction that forms a three-dimensional supramolecular framework by hydrogen bonding and π-π interaction and The electrochemical and electrocatalytic properties of compound 1 were studied.