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为了适应国际上《蒙特利尔议定书》即将禁用CFC与HCFC类物质的紧迫要求,寻求它们的替代物成了当务之急。HFC-125是迄今为止所有用以替代HCFC-22的混合工质中必不可少的一种组份,而其物性研究还十分欠缺,特别是它的表面张力研究尤为少见。因此本文发表了在233.15~333.15K温度范围内,通过精密测量获得的21组HFC-125表面张力实验数据。实验所用的样品纯度为99.98%。这些数据是利用毛细管表面张力实验装置,分别按两种方法─—绝对法和相对法测量计算得到的。不同方法的结果吻合得很好,相对偏差在0.2%以内,绝对偏差小于0.01mN/m,所测得的数据具有很高的可信性。最后还通过对实验数据拟合,提出了该温度范围内HFC-125表面张力与温度间的关联式。
In order to meet the urgent international call for banning CFCs and HCFCs in the Montreal Protocol, the search for their alternatives has become a top priority. HFC-125 is by now an essential component of all mixed refrigerants used to replace HCFC-22, and its physical properties are still lacking. In particular, its surface tension study is especially rare. Therefore, the experimental data of 21 groups of HFC-125 surface tension obtained by the precision measurement in the temperature range 233.15 ~ 333.15K are presented in this paper. The purity of the sample used in the experiment was 99.98%. These data were calculated using capillary surface tension test apparatus, measured by two methods - absolute and relative measurements, respectively. The results of different methods agree well with the relative deviation of 0.2% or less, the absolute deviation of less than 0.01mN / m, the measured data with high credibility. Finally, by fitting the experimental data, the correlation between the surface tension of HFC-125 and temperature in this temperature range is proposed.