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采用TEM、EELS测定了Ti/TiCp复合材料界面相为Ti2C。根据电子衍射理论和晶体学理论确定了Ti2C晶体的晶胞大小和晶胞中Ti、C原子坐标,并讨论了C空位的有序排列规律。Ti2C晶胞中有48个原子:32个Ti原子,16个C原子。Ti原子占据空间群的32e等效位置(x取3/8或7/8),C原子占据空间群的16c或16d等效位置。F111GC原子平面上C空位作有序排列。C原子占有率为3/4和互/4的F111GC原子面交替排列。<111>方向一个周期长度内包含6层Ti原子面和6层C原子面,其排列规律为:
The phase interface of Ti / TiCp composite was Ti2C by TEM and EELS. According to the theory of electron diffraction and crystallography, the unit cell size of Ti2C crystal and the coordinate of Ti and C atoms in the unit cell have been determined, and the ordered arrangement of C vacancies has been discussed. Ti2C unit cell has 48 atoms: 32 Ti atoms, 16 C atoms. The Ti atom occupies the 32e equivalent position of the space group (x takes 3/8 or 7/8) and the C atom occupies the 16c or 16d equivalent position of the space group. On the plane of F111GC, C vacancies are arranged in order. C atom occupancy rate of 3/4 and each / 4 F111GC atomic planes alternately arranged. The length of one cycle of <111> direction contains 6 layers of Ti atomic planes and 6 layers of C atomic planes. The arrangement rule is as follows: